The discovery of Nafion in the 1960s by DuPont served to set the stage for the commencement of themanufacture of unique artificial polymers that exhibit ionic properties. Nafion was developed from a copolymerization reaction pitting tetrafluroethylene (TFE) and sulfonic acid (SO3â€“Â H+) that was attached to a vinyl ether backbone. With these properties, Nafion is referred to as an ionomer i.e. it is ionic in nature and can conduct ionic compounds. Its structure is as shown in the figure below:
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